By Eric G. Derouane, Stanley M. Roberts

Vol. 1 features a file by means of Stanley M. Roberts at the integration of biotransformations into the catalyst portfolio.The process part encompasses a large choice of man-made protocols, equivalent to epoxidations of unsaturated ketones and esters, uneven mark downs of carbon-oxygen double bonds, uneven hydrogenations of carbon-carbon double bonds and different forms of reaction.The featured catalysts contain quite a lot of various fabrics comparable to poly-D-leucine, D-fructose-based dioxiranes, oxaborolidine borane, a few very important titanium and ruthenium complexes in addition to baker's yeast. for every response there are one or numerous certain protocols on how one can organize and hire many of the catalysts.

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R. J. J. Org. , 1998, 63, 6784. 18. , Hosoya, T. and Sano, T. , 1998, 39, 397. 19. Vedejs, E. and Daugulis, O. J. Am. Chem. A. C. , Jr. J. ibid, 1999, 121, 11638. 20. W. and Osswald, S. Tetrahedron Asymmetry, 1997, 8, 2749. 21. A. N. Bioorg. Med. , 1999, 7, 2163. 22. , Mischitz, M. and Kroutil, W. Acta Chem. , 1996, 50, 249; Archelas, A. and Furstoss, R. Ann. Rev. M. Weijers, Tetrahedron: Asymmetry, 1997, 8, 639. 23. , Archelas, A. and Furstoss, R. , 1996, 37, 3319. 24. , Archelas, A. and Furstoss, R.

Eng. Biotechnol. 1999, 63, 146; note that the the integration of biotransformations into catalyst 26. 27. 28. 29. 30. 31. 32. 33. 34. 35. 36. 37. 38. 39. 40. 41. 42. 43. 44. 45. 46. M. B. Tetrahedron: Asymmetry, 1998, 9, 459. F. and Tokunaga, M. A. N. J. Am. Chem. , 1999, 121, 4147. J. and Crosby, J. , 1996, 37, 6001. S. R. Tetrahedron: Asymmetry, 1997, 8, 2649. , Ikeda, H. and Ohta, H. Synlett, 1997, 983. J. A. Tetrahedron: Asymmetry, 1997, 8, 1049. J. K. Cambridge University Press, New York, 1995, Chapter 2, p.

1998, 37, 1931. 64. W. L. and Zhang, X. J. Org. , 1998, 63, 8100. 65. , Goddard, R. -H. S. Chem. Comm. H. S. , Borneo, A. and Knochel, P. ibid, 1998, 39, 8073. 66. L. G. J. Am. Chem. , 1997, 119, 9570. 67. K. C. J. Org. , Ohff, M. and Riepe, A. Tetrahedron, 1996, 52, 15079. the integration of biotransformations into catalyst 43 68. J. and Ohff, M. Tetrahedron: Asymmetry, 1999, 10, 3341. 69. , Yamamoto, K. and Takahashi, T. J. Org. , 1998, 63, 428. 70. , Kluge, R. G. Tetrahedron Asymmetry, 1998, 9, 4341.

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