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Additional info for Molecular Imprinting of Polymers
12 with permission. ©1994 Elsevier Science B. V. controlled structure is expected to be kept even after the removal of the template on the basis of its covalent nature. However, silica has limitations. Among metal oxides, silica is known to possess a substantially inactive surface. Usually, adsorption on silica is weak and the silica surface has few functions. As shown below, introduction of an additional metal element or functional group is required to construct a reaction field suitable for various practical purposes such as electrochemical sensing and catalysis.
Kodakari N, Tomita K, Iwata K et al. Molecular sieving silica overlayer on g-alumina:the structure and acidity controlled by the template molecule. Langmuir 1998; 14(16):4623-4629. 40 Molecular Imprinting of Polymers 89. Kodakari N, Sakamoto T, Shinkawa K et al. Molecular-sieving gas sensor prepared by chemical vapor deposition of silica on tin oxide using an organic template. Bull Chem Soc Jpn 1998; 71(2):513-519. 90. Tanimura T, Katada N, Niwa M. Molecular shape recognition by tin oxide chemical sensor coated with silica overlayer precisely designed using organic molecule as template.
Cajal Y, Svedsen A, Girona V et al. Interfacial control of lid opining in thermomyces lanuginonsa lipase. Biochemistry 2000; 39:413-423. 43. Margolin AL. Novel crystalline catalysts. Trends Biotechnol 1996; 4:223-230. 44. Asanuma H, Kakazu M, Shibata M et al. Molecularly imprinted polymer of β-cyclodextrin for the efficient recognition of cholesterol. Chem Commun 1997; 1971-1972. 45. Asanuma H, Kajiya K, Hishiya T et al. Molecularly imprinting of cyclodextrin in water for the recognition of peptides.