By M. Green, M. J. Almond, D. A. Armitage
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Additional resources for Organometallic chemistry. Electronic book .: a review of the literature published during 1996
Example text
Alcohols and thiols were both used as proton transfer reagents (reaction 3) to give bimetallic compounds with bridging chalcogenolate ligands, while carboxylate derivatives were prepared by metathesis. There were two reports detailing the reaction of Cp3Ln compounds with thiols. " The same structural observation was noted in the synthesis and characterization of a series of Cp2LnSR compounds (Ln = Dy, Yb; R = n-Bu, n(11) was determined, Pr). 699(3) A) Yb-S bond lengths. Bond geometries about the S atoms are, as is typical, consistent with a significant amount of pure p-hybridization.
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