By Andreas Hirsch, Dr. rer. nat
Even if man made fullerenes have merely been round for many years, there are literally thousands of medical articles facing them. this can be the 1st monograph within the box and hence represents an essential resource of data summarizing crucial and basic elements of the natural and organometallic chemistry of the fullerenes. The publication is logically prepared in order that details is straightforward to retrieve, and the fashion lends itself to easy analyzing and to studying extra concerning the chemical homes of a kin of molecules that represent new construction blocks for novel architectures in. Read more... The Chemistry of the Fullerenes; Contents; bankruptcy 1. The mum or dad Fullerenes; bankruptcy 2. aid; bankruptcy three. Nucleophilic Additions; bankruptcy four. Cycloadditions; bankruptcy five. Hydrogenation; bankruptcy 6. Radical Additions; bankruptcy 7. Transition steel complicated Formation; bankruptcy eight. Oxidation and Reactions with Electrophiles; bankruptcy nine. rules and views of Fullerene Chemistry; Index
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This reflects the changes of the orbital energies of the LUMO and LUMO+l with diminished degeneracy”. For the dianion c602- an ESR spectrum consistent with a triplet ground state (S = 1) was observed [Fig. 21924, which is the highest spin state for any c60”-. 4 41 82u Molecular orbital diagram for Cm2- Additional one-electron reductions lead to a S = 1/2 ground state for the trianion C&-, to a diamagnetic tetraanion C604-, a pentaanion C605- with a spin of 1/2 and finally to the diamagnetic hexaanion C6o6-[Fig.
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