By M. S. Tyagi (auth.), B. L. Sharma (eds.)

The present-day semiconductor expertise will be impossible with out large use of Schottky barrier junctions. inspite of an outstanding publication through Professor E.H. Rhoderick (1978) facing the fundamental ideas of steel­ semiconductor contacts and some fresh assessment articles, the necessity for a monograph on "Metal-Semiconductor Schottky Barrier Junctions and Their purposes" has lengthy been felt via scholars, researchers, and technologists. It was once during this context that the assumption of publishing this kind of monograph via Mr. Ellis H. Rosenberg, Senior Editor, Plenum Publishing company, used to be thought of very well timed. as a result of quite a few and sundry purposes of Schottky barrier junctions, the duty of bringing it out, besides the fact that, appeared tricky at first. After discussions at a variety of degrees, it used to be deemed applicable to incorporate in basic terms these ordinary functions which have been tremendous wealthy in R&D and nonetheless posed many demanding situations in order that it may be introduced out within the stipulated time-frame. protecting in view the bigger curiosity, it used to be additionally necessary to have the various themes of Schottky barrier junctions written by way of experts.

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However, as time proceeds the traps in the depletion region occupied by the electrons will be emptied. These electrons will be swept out of the depletion region, causing an increase in the positive charge density and thus reducing the depletion region widths. (70) Study of deep levels using capacitance transient techniques has developed into an important tool known as deep level transient spectroscopy (DLTS). A review of this technique is given by Miller, Lang, and Kimerling. (71) 6. 1. Transport Mechanisms The current flows in a Schottky barrier diode because of charge transport from the semiconductor to the metal or in the reverse direction.

However, as time proceeds the traps in the depletion region occupied by the electrons will be emptied. These electrons will be swept out of the depletion region, causing an increase in the positive charge density and thus reducing the depletion region widths. (70) Study of deep levels using capacitance transient techniques has developed into an important tool known as deep level transient spectroscopy (DLTS). A review of this technique is given by Miller, Lang, and Kimerling. (71) 6. 1. Transport Mechanisms The current flows in a Schottky barrier diode because of charge transport from the semiconductor to the metal or in the reverse direction.

44) (b) It has been observed(45) that when metal films thicker than about 450A are evaporated onto cleaved surfaces of covalent semiconductors in ultrahigh vacuum, an intermixing of metal and semiconductor atoms takes place even at room temperature. (46) The chemical bonding in this interfacial region is different from that in the bulk semiconductor and this may give rise to interfacial states in the band gap of the semiconductor and the subsequent pinning of the Fermi levet<20) (c) A recent study of silver contacts on GaAs surfaces cleaned by ion bombardment and annealing has shown(47) that the surface Fermi level is pinned by donor and acceptor type surface states located near the center of the gap.

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